Welcome to the PlayStation Community.
Is there any way to email Playstation Network Support?
Sorry but the option to email Sony customer support was removed some time ago, here's a link to the current options open to you now.
Is there anything we can assist you with, we're pretty knowledgeable here, well some of us ?
Here's Sony's phone number, you can also click on the 'live chat' link in my signature if you would prefer to chat to a Sony representative directly.
Mon - Sun 6:00AM - 10:00PM Pacific
Customer Service - 1-800-345-SONY (7669)
Account & billing Support -1-877-971-SONY (7669)
Available Mon to Fri 8am - 8pm PST