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I very much doubt you will be playing Ruin at the Vita's launch as its not a launch game. It's not due out until after launch and is more likely to be launch window or possibly beyond.
The game I'll be playing first is Uncharted: Golden Abyss.
I already have Resistance: Burning Skies preordered and that will be my first but I will more then likely be pre ordering a few more from that list.
I take it then you won't be playing any games at launch ?
I preordered the 3g/wifi bundle, and the first game i'll play will be wipeout 2048.
I might try BlazBlue or Gravity Rush first. I'll get Disgaea, Uncharted, & LBP later on.
Uncharted: Golden Abyss for me.
On launch day I'll be getting Uncharted: Golden Abyss, Ridge Racer, Ninja Gaiden Sigma Plus, and Rayman Origins. Idk which I'll play first though.
I usually play the game that I least want to play first and if I get the First Edition Bundle it would be Little Deviants.