This same issue the original poster mentioned, has been a problem since they updated the Playstation Store. On top of that, I get a weird download error that prevents me from downloading anything unless I turn off my PS3 and turn it back on, ANNOYING.
Give us our old PSN back, or at least let it be an option.
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If a game has an in game store (mass effect, battlefield, etc) when you purchase content from in game it still uses the old store (the old store IS still there, but the app on the XMB will only take you to the new one) and when you purchase this way, it will still ask if you want the items bought posted on facebook