05-13-2013 06:35 PM
05-13-2013 07:00 PM - edited 05-13-2013 07:01 PM
No, because the Vita does not recognize Media Go. You need to download a game with either a PS3 and transfer it to the Vita, or download directly to the Vita from the PSN Store. Those are the only valid ways to get a game to your PS Vtia.
The game will most likely be available through the Download list, so yeah it's still possible to purchase stuff from there for your vita. (That is however if the PSP game is compatible with the vita)