Well you had me beat with Father. I agree that he is the most bad dudes in anime/manga, unlike that lame and pathetic Dante from the first FMA anime. And for me he is the BEST villain anime/manga period. I would have to correct with one thing in regards to Father. He didn't create a circle around the country but made the country with the circle in mind since he was ruling it since the start.
For another villain I would say... Saburota Todo from Blue Exorcist. While Satan is just a big bad with nothing too detailed about him and Mephisto is in a gray area we have Saburota. Not seeming to work for anyone a man bored with living the life like his family and living among demons. Plus he plays off of Yukio's on weaknesses and expericences being living in the shadow of his father and bother he feels that he can relate to Yukio. And some how force Yukio to the demon side without having to rely on the whole Yukio is the son of satan without his powers deal. I'm just so surprised that I like a villain that is more or less just for this arc, and to show that in Blue Exorcist that anyone could become a demon if they fall so far.
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